The Art of Nanoparticle Design: Unconventional Morphologies for Advancing Luminescent Technologies

Abstract The advanced design of rare‐earth‐doped (RE‐doped) fluoride nanoparticles has expanded their applications ranging from anticounterfeiting luminescence and contactless temperature measurement to photodynamic therapy. Several recent studies have focused on developing rare morphologies of RE‐doped nanoparticles. Distinct physical morphologies of RE‐doped fluoride materials set them apart from contemporary nanoparticles. Every unusual structure holds the potential to dramatically improve the physical performance of nanoparticles, resulting in a remarkable revolution and a wide range of applications. This comprehensive review serves as a guide offering insights into various uniquely structured nanoparticles, including hollow, dumbbell‐shaped, and peasecod‐like forms. It aims to cater to both novices and experts interested in exploring the morphological transformations of nanoparticles. Discovering new energy transfer pathways and enhancing the optical application performance have been long‐term challenges for which new solutions can be found in old papers. In the future, nanoparticle morphology design is expected to involve more refined microphysical methods and chemically‐induced syntheses. Targeted modification of nanoparticle morphology and the aggregation of nanoparticles of various shapes can provide the advantages of different structures and enhance the universality of nanoparticles.