Organic Synthetic Photonic Systems with Reconfigurable Parity–Time Symmetry Breaking for Tunable Single‐Mode Microlasers

Synthetic photonic materials exploiting the quantum concept of parity-time (PT) symmetry lead to an emerging photonic paradigm-non-Hermitian photonics, which is revolutionizing the photonic sciences. The non-Hermitian photonics dealing with the interplay between gain and loss in PT synthetic photonic material systems offers a versatile platform for advancing microlaser technology. However, current PT-symmetric microcavity laser systems only manipulate imaginary parts of the refractive indices, suffering from limited laser spectral bandwidth. Here, an organic composite material system is proposed to synthesize reconfigurable PT-symmetric microcavities with controllable complex refractive indices for realizing tunable single-mode laser outputs. A grayscale electron-beam direct-writing technique is elaborately designed to process laser dye-doped polymer films in one single step into microdisk cavities with periodic gain and loss distribution, which enables thresholdless PT-symmetry breaking and single-mode laser operation. Furthermore, organic photoisomerizable compounds are introduced to reconfigure the PT-symmetric systems in real-time by tailoring the real refractive index of the polymer microresonators, allowing for a dynamically and continuously tunable single-mode laser output. This work fundamentally enhances the PT-symmetric photonic systems for innovative design of synthetic photonic materials and architectures.