原子单位
制氢
纳米技术
氢
生产(经济)
材料科学
比例(比率)
化学
化学工程
物理
工程类
有机化学
量子力学
宏观经济学
经济
作者
Jun Cao,Yi Lu,Yu Wang,Yiwei Shi,Hong Sun,Jingjing Wang,Yingying Zheng,Jiaqi Pan,Wenwu Zhong,Chaorong Li
标识
DOI:10.1016/j.jallcom.2024.174453
摘要
Introducing defects into Pd-based metallene has been shown to significantly enhance its electrocatalytic performance. In this study, we embedded a new type of atomic-scale cavities into the basal plane of PdMo bimetallene (c-PdMo) through precise etching. These cavities introduced tensile strain and increased the generalized coordination number (CN̅), resulting in superior performance in formate oxidation reaction (FOR) and methanol oxidation reaction (MOR), with mass activities of 5.01 mAμgNM−1 and 5.38 mAμgNM−1, respectively. Notably, a two-electrode system comprising commercial Pt/C and c-PdMo coated on carbon paper achieved cell voltages of only 0.517 V and 0.362 V at 10 mA cm−2 for FOR and MOR, respectively. Additionally, density functional theory calculations revealed that the deliberate lattice tensile strain and enhanced coordination numbers reduced the D-band center of defective PdMo, which improved OH adsorption and reduced CO adsorption, thus optimizing FOR and MOR catalysis on the surface of c-PdMo bimetallene.
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