Low shrinkage polyimide aerogel cross-linked with amino-functionalized hollow glass microbeads for thermal and acoustic insulation

As a nanoporous material, polyimide (PI) aerogels have excellent thermal and acoustic properties. However, their high air flow resistance is detrimental to the development of their acoustic properties. To enhance the thermal and acoustic insulation properties of PI aerogels, we have selected hollow glass microbeads (HGM) with a low thermal conductivity coefficient to be combined with the PI aerogel, leading to the fabrication of PI/HGM aerogel composite materials. In this study, there are two preprocessing methods for HGM: untreated and aminized (HGM-NH2). These were then individually combined with PI aerogel to fabricate two distinct PI/HGM composite aerogels: a physically blended variant (PIHGM) and a chemically bonded one (PHN). The thermal insulation and acoustic properties of these two composite aerogels were compared. The results show that HGM-NH2 not only functions as a cross-linking agent but also plays a key role in forming the three-dimensional network structure, which effectively reduces the shrinkage rate and density of the composite aerogel. Moreover, the thermal conductivity of PHN reached a low of 27.92 mW m⁻1 K⁻1, which is a reduction compared to PIHGM's thermal conductivity of 29.83 mW m⁻1 K⁻1. Moreover, the PHN composite aerogel with 10% HGM addition exhibited an average sound insulation level that was 120% higher than that of PIHGM. The method of incorporating pore structures with different scales also offers valuable insights for enhancing the sound insulation performance of other materials.