合成气
二氧化碳重整
甲烷
催化作用
热液循环
吸附
碳纤维
化学工程
碳纳米管
无机化学
甲烷转化炉
化学
X射线光电子能谱
氧化物
材料科学
纳米技术
蒸汽重整
有机化学
制氢
复合材料
工程类
复合数
作者
Zheng‐Cai Jiang,Yuchen Shi,Yonghui Bai,Xudong Song,Jiaofei Wang,Peng Lv,Shiyong Wu,Weiguang Su
出处
期刊:Fuel
[Elsevier]
日期:2022-12-17
卷期号:337: 127136-127136
被引量:13
标识
DOI:10.1016/j.fuel.2022.127136
摘要
Hydrothermal synthesis of carbon nanotubes (CNTs) supported by Co catalysts with low nitrogen contents was used for methane reforming by CO2. The physicochemical properties of Co/N-CNTs catalysts were characterized by XRD, BET, Raman, TEM, H2-TPR, CO2-TPD and XPS. Highest total N amount and pyridinic N content were obtained at an optimal hydrothermal condition. Meanwhile, it is capable to convert CH4 into 92.9% and CO2 into 96.4% on the best Co/N-CNTs catalyst. N doping strengthened the interaction between Co oxide and CNTs, and enhanced carbon defect concentration and CO2 adsorption capacity, which was beneficial to increase the CH4 and CO2 conversions. Carbon defects may be conducive to the activation of CH4. It was supposed that the synergistic effect between pyridinic N and carbon defects significantly improved the methane dry reforming activity of the Co/N-CNTs catalysts.
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