单独一对
荧光粉
材料科学
氢键
封面(代数)
结晶学
光化学
硼酸
磷光
化学
分子
荧光
有机化学
物理
光学
工程类
机械工程
光电子学
作者
Haifeng Zheng,Peisheng Cao,Yanying Wang,Xiaomei Lü,Peng Wu
标识
DOI:10.1002/anie.202103677
摘要
The impressive and unexpected long-lived room-temperature phosphorescence of boric acid (H3BO3) is unveiled by Peng Wu and co-workers in their Research Article on page 9500. Unlike traditional metallic inorganic or aromatic organic phosphors, the phosphorescence originates from the weak conjugation of lone pair electrons from O atoms. The vacant pz orbital of B and the regular arrangement in the crystalline state with layer-like packing through abundant hydrogen bonding are found to contribute to the long-lived emission.
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