Solvent-induced structural transformation from heptanuclear to decanuclear [Co–Ln] coordination clusters: trapping of unique counteranion and understanding of aggregation pathways

The MeCN solvent-induced transformations of heptanuclear LnIII3CoII2CoIII2⁺ cationic aggregates, associated with literature unknown Ln(iii)-pivalate-based counter anions, to decanuclear LnIII3CoII3/2CoIII4/5 clusters have been investigated.