Catalytic decomposition and mass transfer of aqueous ozone promoted by Fe-Mn-Cu/γ-Al2O3 in a rotating packed bed

This study investigated catalytic decomposition and mass transfer of aqueous ozone promoted by Fe-Mn-Cu/γ-Al2O3 (Cat) in a rotating packed bed (RPB) for the first time. The results showed that the value of the overall decomposition rate constant of ozone (Kc) and overall volumetric mass transfer coefficient (KLa) are 4.28 × 10−3 s−1 and 11.60 × 10−3 s−1 respectively at an initial pH of 6, β of 40, CO3(g) of 60 mg·L−1 and QL of 85 L·h−1 in deionized water, respectively. Meanwhile, the Kc and KLa values of Fenhe water are 0.88 × 10−3 s−1 and 2.51 × 10−3 s−1 lower than deionized water, respectively. In addition, the Kc and KLa values in deionized water for the Cat/O3-RPB system are 44.86% and 47.41% higher than that for the Cat/O3-BR (bubbling reactor) system, respectively, indicating that the high gravity technology can facilitate the decomposition and mass transfer of ozone in heterogeneous catalytic ozonation and provide some insights into the industrial wastewater.