范德瓦尔斯力
哈梅克常数
范德瓦尔斯曲面
范德瓦尔斯半径
范德瓦尔斯株
物理
氢
统计物理学
原子物理学
经典力学
量子力学
分子
作者
Eric Cancès,Rafaël Coyaud,L. Ridgway Scott
出处
期刊:Communications in Mathematical Sciences
[International Press of Boston, Inc.]
日期:2023-01-01
卷期号:21 (4): 915-948
标识
DOI:10.4310/cms.2023.v21.n4.a2
摘要
We extend a method (E. Cances and L.R. Scott, SIAM J. Math. Anal., 50, 2018, 381--410) to compute more terms in the asymptotic expansion of the van der Waals attraction between two hydrogen atoms. These terms are obtained by solving a set of modified Slater-Kirkwood partial differential equations. The accuracy of the method is demonstrated by numerical simulations and comparison with other methods from the literature. It is also shown that the scattering states of the hydrogen atom, that are the states associated with the continuous spectrum of the Hamiltonian, have a major contribution to the C$_6$ coefficient of the van der Waals expansion.
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