多硫化物
材料科学
硫黄
电池(电)
电解质
溶解
储能
氧化还原
纳米技术
锂(药物)
化学工程
动力学
锂硫电池
碳纳米管
电极
化学
冶金
物理化学
功率(物理)
内分泌学
工程类
物理
医学
量子力学
作者
Jiayi Wang,Yan Zhao,Gaoran Li,Dan Luo,Jiabing Liu,Yongguang Zhang,Xin Wang,Lingling Shui,Zhongwei Chen
出处
期刊:Nano Energy
[Elsevier]
日期:2021-02-16
卷期号:84: 105891-105891
被引量:94
标识
DOI:10.1016/j.nanoen.2021.105891
摘要
Lithium/sulfur (Li/S) battery has been regarded as promising candidate for next-generation energy storage systems due to the high energy density. The big obstacle to realize the practical application of Li/S battery is to synchronously accelerate the redox kinetics and restrain the dissolution of polysulfides into the electrolyte. On this account, ZnS nanotubes with abundant sulfur vacancies (ZnS1−x) are constructed and deposited onto a freestanding carbon cloth electrode for Li/S batteries. The combination of architectural and sulfur-vacancy engineering regulates the electronic structure of ZnS as well as its interactions with active sulfur, thus by facilitates ion/electron transfer, immobilizes lithium polysulfide, and accelerates sulfur reaction kinetics. As a consequence, a capacity of 1043 mAh g−1 is obtained under a low current density of 0.2 C, as well as a capacity retention of 524 mAh g−1 over 500 cycles at 1 C. This work presents a convenient and effective material design strategy to improve the performance of Li/S batteries and promote the practical process.
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