化学
马尔科夫尼科夫法则
区域选择性
催化作用
光催化
产量(工程)
醋酸
可见光谱
烯烃
光化学
组合化学
有机化学
光催化
物理
光电子学
冶金
材料科学
出处
期刊:Organic Letters
[American Chemical Society]
日期:2019-11-05
卷期号:21 (22): 9236-9240
被引量:61
标识
DOI:10.1021/acs.orglett.9b03636
摘要
The anti-Markovnikov hydrosulfonylation of unactivated alkenes with sodium sulfinates was realized via [Ir(dF(CF3)ppy)2(dtbbpy)]PF6-mediated visible light photoredox catalysis. The presence of an acid such as acetic acid is essential for the reaction to take place. A variety of unactivated alkenes can be transformed into sulfones with good yield and high regioselectivity using this reaction, which is proposed to proceed by a radical mechanism.
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