Designing UiO-66-Based Superprotonic Conductor with the Highest Metal–Organic Framework Based Proton Conductivity

质子 电导率 材料科学 烷基 导电体 侧链 质子导体 活化能 金属有机骨架 热传导 电解质 导线 化学工程 化学 物理化学 复合材料 聚合物 有机化学 电极 吸附 工程类 物理 量子力学
作者
Subhabrata Mukhopadhyay,Joyashish Debgupta,Chandani Singh,Rudraditya Sarkar,Olivia Basu,Samar K. Das
出处
期刊:ACS Applied Materials & Interfaces [American Chemical Society]
卷期号:11 (14): 13423-13432 被引量:192
标识
DOI:10.1021/acsami.9b01121
摘要

Metal-organic framework (MOF) based proton conductors have received immense importance recently. The present study endeavors to design two post synthetically modified UiO-66-based MOFs and examines the effects of their structural differences on their proton conductivity. UiO-66-NH2 is modified by reaction with sultones to prepare two homologous compounds, that is, PSM 1 and PSM 2, with SO3H functionalization in comparable extent (Zr:S = 2:1) in both. However, the pendant alkyl chain holding the -SO3H group is of different length. PSM 2 has longer alkyl chain attachment than PSM 1. This difference in the length of side arms results in a huge difference in proton conductivity of the two compounds. PSM 1 is observed to have the highest MOF-based proton conductivity (1.64 × 10-1 S cm-1) at 80 °C, which is comparable to commercially available Nafion, while PSM 2 shows significantly lower conductivity (4.6 × 10-3 S cm-1). Again, the activation energy for proton conduction is one of the lowest among all MOF-based proton conductors in the case of PSM 1, while PSM 2 requires larger activation energy (almost 3 times). This profound effect of variation of the chain length of the side arm by one carbon atom in the case of PSM 1 and PSM 2 was rather surprising and never documented before. This effect of the length of the side arm can be very useful to understand the proton conduction mechanism of MOF-based compounds and also to design better proton conductors. Besides, PSM 1 showed proton conductivity as high as 1.64 × 10-1 S cm-1 at 80 °C, which is the highest reported value to date among all MOF-based systems. The lability of the -SO3H proton of the post synthetically modified UiO-66 MOFs has theoretically been determined by molecular electrostatic potential analysis and theoretical p Ka calculation of models of functional sites along with relevant NBO analyses.
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