B1g -Phonon Anomaly Driven by Fermi Surface Instability at Intermediate Temperature in YBa2

We performed temperature- and doping-dependent high-resolution Raman spectroscopy experiments on YBa_{2}Cu_{3}O_{7-δ} to study B_{1g} phonons. The temperature dependence of the real part of the phonon self-energy shows a distinct kink at T=T_{B1g} above T_{c} due to softening, in addition to the one due to the onset of the superconductivity. T_{B1g} is clearly different from the pseudogap temperature with a maximum in the underdoped region and resembles charge density wave onset temperature, T_{CDW}. We attribute the B_{1g}-phonon softening to an energy gap on the Fermi surface induced by a charge density wave order, which is consistent with the results of a recent electronic Raman scattering study. Our work demonstrates a way to investigate Fermi surface instabilities above T_{c} via phonon Raman studies.