偏最小二乘回归
过度拟合
多元统计
真菌毒素
校准
化学计量学
数学
生物系统
统计
化学
食品科学
生物
计算机科学
人工智能
色谱法
人工神经网络
作者
Della Riccia Giacomo,Stefania Del Zotto
出处
期刊:Food Chemistry
[Elsevier]
日期:2013-07-12
卷期号:141 (4): 4289-4294
被引量:38
标识
DOI:10.1016/j.foodchem.2013.07.021
摘要
Fumonisins are mycotoxins produced by Fusarium species that commonly live in maize. Whereas fungi damage plants, fumonisins cause disease both to cattle breedings and human beings. Law limits set fumonisins tolerable daily intake with respect to several maize based feed and food. Chemical techniques assure the most reliable and accurate measurements, but they are expensive and time consuming. A method based on Near Infrared spectroscopy and multivariate statistical regression is described as a simpler, cheaper and faster alternative. We apply Partial Least Squares with full cross validation. Two models are described, having high correlation of calibration (0.995, 0.998) and of validation (0.908, 0.909), respectively. Description of observed phenomenon is accurate and overfitting is avoided. Screening of contaminated maize with respect to European legal limit of 4 mg kg(-1) should be assured.
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