A High‐Performance Gas‐Separation Membrane Containing Submicrometer‐Sized Metal–Organic Framework Crystals

Angewandte Chemie International EditionVolume 49, Issue 51 p. 9863-9866 Communication A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal–Organic Framework Crystals† Dr. Tae-Hyun Bae, Dr. Tae-Hyun Bae School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorJong Suk Lee, Jong Suk Lee School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorDr. Wulin Qiu, Dr. Wulin Qiu School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorProf. Dr. William J. Koros, Prof. Dr. William J. Koros School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorProf. Dr. Christopher W. Jones, Corresponding Author Prof. Dr. Christopher W. Jones christopher.jones@chbe.gatech.edu School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorProf. Dr. Sankar Nair, Corresponding Author Prof. Dr. Sankar Nair sankar.nair@chbe.gatech.edu School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this author Dr. Tae-Hyun Bae, Dr. Tae-Hyun Bae School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorJong Suk Lee, Jong Suk Lee School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorDr. Wulin Qiu, Dr. Wulin Qiu School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorProf. Dr. William J. Koros, Prof. Dr. William J. Koros School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorProf. Dr. Christopher W. Jones, Corresponding Author Prof. Dr. Christopher W. Jones christopher.jones@chbe.gatech.edu School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this authorProf. Dr. Sankar Nair, Corresponding Author Prof. Dr. Sankar Nair sankar.nair@chbe.gatech.edu School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA 30332-0100 (USA), Fax: (+1) 404-894-4200Search for more papers by this author First published: 16 November 2010 https://doi.org/10.1002/anie.201006141Citations: 547 † This work was supported by ExxonMobil Research and Engineering. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Well matched: Submicrometer-sized metal–organic framework (MOF) crystals (ZIF-90) were synthesized by a nonsolvent-induced crystallization technique and incorporated in mixed-matrix gas-separation membranes. ZIF-90/6FDA-DAM membranes (empty pink circle; beyond the upper bound for polymer membranes) show unprecedented high performance for CO2/CH4 separation by a MOF-based membrane. The key is the combination of the highly selective MOF and a highly permeable polymer. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201006141_sm_miscellaneous_information.pdf376.4 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume49, Issue51December 17, 2010Pages 9863-9866 RelatedInformation