化学
催化作用
不对称氢化
贵金属
多相催化
组合化学
金属
对映选择合成
有机化学
纳米技术
材料科学
作者
Fabian Meemken,Alfons Baiker
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2017-09-05
卷期号:117 (17): 11522-11569
被引量:283
标识
DOI:10.1021/acs.chemrev.7b00272
摘要
The ease of separation, simple regeneration, and the usually high stability of solid catalysts facilitating continuous production processes have stimulated the development of heterogeneous asymmetric hydrogenation catalysis. The simplest and so far most promising strategy to induce enantioselectivity to solid metal catalysts is their modification by chiral organic compounds, as most prominently represented by the cinchona-modified Pt and Pd catalysts for the asymmetric hydrogenation of activated C═O and C═C bonds. In this Review, we provide a systematic account of the research accomplished in the past decade on noble metal-based heterogeneous asymmetric hydrogenation of prochiral C═O and C═C bonds, including all important facets of these catalytic systems. The advances made are critically analyzed, and future research challenges are identified.
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