激光诱导击穿光谱
钴
材料科学
光谱学
干扰(通信)
光学
荧光光谱法
激光器
校准
激光诱导荧光
分析化学(期刊)
灵敏度(控制系统)
荧光
校准曲线
检出限
化学
物理
电子工程
环境化学
电信
频道(广播)
色谱法
量子力学
计算机科学
冶金
工程类
作者
Ran Zhou,Ke Liu,Zhiyang Tang,Peiyuan Gao,Jiujiang Yan,Xiangyou Li
出处
期刊:Applied Optics
[The Optical Society]
日期:2021-09-16
卷期号:60 (29): 9062-9062
被引量:5
摘要
Conventional laser-induced breakdown spectroscopy could not conduct high-sensitivity determination of available cobalt due to spectral interference and weak spectral intensity. To improve the poor detection sensitivity of available cobalt in soil, available cobalt was extracted from soil and prepared. Laser-induced breakdown spectroscopy assisted with laser-induced fluorescence was introduced to excite and detect the cobalt element. The results showed that coefficients of the calibration curve for the available cobalt element could reach 0.9991, and the limits of detection could reach 0.005 mg/kg in soil under optimized conditions, which were all much better than conventional LIBS and reach the international minimum detection standards. This work provides a possible approach for detecting available trace elements in soil.
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