Models of adsorption-induced deformation: ordered materials and beyond

吸附 变形(气象学) 表征(材料科学) 材料科学 多孔性 多孔介质 毛细管冷凝 介孔材料 维数(图论) 纳米技术 复合材料 化学 数学 物理化学 有机化学 纯数学 催化作用
作者
A. L. Kolesnikov,Yury A. Budkov,Gennady Y. Gor
出处
期刊:Journal of Physics: Condensed Matter [IOP Publishing]
卷期号:34 (6): 063002-063002 被引量:14
标识
DOI:10.1088/1361-648x/ac3101
摘要

Adsorption-induced deformation is a change in geometrical dimensions of an adsorbent material caused by gas or liquid adsorption on its surface. This phenomenon is universal and sensitive to adsorbent properties, which makes its prediction a challenging task. However, the pure academic interest is complemented by its importance in a number of engineering applications with porous materials characterization among them. Similar to classical adsorption-based characterization methods, the deformation-based ones rely on the quality of the underlying theoretical framework. This fact stimulates the recent development of qualitative and quantitative models toward the more detailed description of a solid material, e.g. account of non-convex and corrugated pores, calculations of adsorption stress in realistic three-dimension solid structures, the extension of the existing models to new geometries, {\sl etc}. The present review focuses on the theoretical description of adsorption-induced deformation in micro and mesoporous materials. We are aiming to cover recent theoretical works describing the deformation of both ordered and disordered porous bodies.

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