吸附
变形(气象学)
表征(材料科学)
材料科学
多孔性
多孔介质
毛细管冷凝
介孔材料
维数(图论)
纳米技术
复合材料
化学
数学
物理化学
有机化学
纯数学
催化作用
作者
A. L. Kolesnikov,Yury A. Budkov,Gennady Y. Gor
标识
DOI:10.1088/1361-648x/ac3101
摘要
Adsorption-induced deformation is a change in geometrical dimensions of an adsorbent material caused by gas or liquid adsorption on its surface. This phenomenon is universal and sensitive to adsorbent properties, which makes its prediction a challenging task. However, the pure academic interest is complemented by its importance in a number of engineering applications with porous materials characterization among them. Similar to classical adsorption-based characterization methods, the deformation-based ones rely on the quality of the underlying theoretical framework. This fact stimulates the recent development of qualitative and quantitative models toward the more detailed description of a solid material, e.g. account of non-convex and corrugated pores, calculations of adsorption stress in realistic three-dimension solid structures, the extension of the existing models to new geometries, {\sl etc}. The present review focuses on the theoretical description of adsorption-induced deformation in micro and mesoporous materials. We are aiming to cover recent theoretical works describing the deformation of both ordered and disordered porous bodies.
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