Organic/Inorganic Hybrid Boosting Energy Harvesting Based on the Photothermoelectric Effect

Attracted by the capability of light to heat and electricity conversion, the photothermoelectric (PTE) effect has drawn great attention in the field of energy conversion and self-powered electronics. However, it still requires effective strategies to convert electricity from light based on the corresponding photothermoelectric generator. Herein, considering the broad photoresponse and large Seebeck effect of tellurium nanowires (Te NWs) as well as the high electrical conductivity of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), PEDOT:PSS/Te NW hybrid thin films were fabricated to enhance the conversion efficiency by the photothermoelectric effect with respect to single thermoelectric performance. A detailed comparison has been achieved between the photothermoelectric and thermoelectric properties induced by light illumination and heating plates through current–voltage (I–V) transport, respectively. PEDOT:PSS/Te NW hybrid films also show an enhanced photothermal harvesting compared to pure PEDOT:PSS. A photothermoelectric device was assembled based on the as-fabricated PEDOT:PSS/Te NW hybrid films with 90 wt% Te NWs and achieved a competitive output power density with good stability, which may provide insights into improving solar energy harvesting-based photothermoelectric conversion by organic/inorganic hybrids.