Preparation and characterization of lignin-derived hard templated carbon(s): Statistical optimization and methyl orange adsorption isotherm studies

In this study, lignin-derived zeolite templated carbon materials were fabricated to remove the organic contaminant, methyl orange. Response surface methodology with Box-Behnken design was used to optimize the adsorption parameters. Based on Box-Behnken design, a quadratic model was developed to correlate the adsorption variables with the response, removal efficiency. Analysis of variance revealed the adsorbent dosage as the most influential adsorption variable. Lignin derived ZSM-5 (PZ) and mordenite (PM) templated carbon materials exhibited high surface area; 476.0 and 716.0 m2/g respectively. The maximum theoretical adsorption capacity of PZ and PM for methyl orange was 514.0 and 225.0 mg/g, respectively. The experimental kinetic data best fitted to pseudo-second-order model for both the adsorbents. PZ adsorbent was also utilized to treat real wastewater containing dyes and achieved 40 % methyl orange removal efficiency. Adsorption thermodynamic study revealed the process as spontaneous, exothermic and also indicated the increment in entropy after adsorption.