期刊:Science of Advanced Materials [American Scientific Publishers] 日期:2024-04-01卷期号:16 (4): 468-474
标识
DOI:10.1166/sam.2024.4654
摘要
Bamboo activated carbon (BAC) has excellent specific capacitance among electrode materials, but the important challenges of it are the insufficient energy density and power density currently. Herein, a facile method for the preparation of strong performance MnO/Mn 3 O 4 /C composites by putting BAC into KMnO 4 solution and annealing in tube furnace. Interestingly, by controlling the reaction time and substrate concentration of BAC and KMnO 4 , it is possible to control not only the amount of MnO x doping, but also to change the ratio between MnO x , and thereby the electrochemical properties of MnO x /C was improved. Since BAC had a bilayer capacitance and manganese oxides could bring pseudo-capacitance to the materials, when the experimental conditions were reaction time and concentration of 20 min and 20 g/L respectively, the Mn content of the composite was 19.91% and it also had a excellent performance with 422.8 F/g of specific capacitance. In addition, the power and energy density were 30.76 Wh/kg and 3460 W/kg, respectively. It provided a basis for effectively improving the electrochemical performance of carbon-based electrode materials.