材料科学
竹子
氧化锰
电化学
锰
电极
活性炭
碳纤维
氧化物
化学工程
无机化学
冶金
复合材料
复合数
吸附
有机化学
化学
物理化学
工程类
作者
Wenxuan Tong,Ting Yu,Yanying Xiong,Yin-ni Qiu,Yun-qi Yu,Cuiping Wen,Zhancai Zheng,Lihui Chen,Liulian Huang,Xiaxing Zhou
出处
期刊:Science of Advanced Materials
[American Scientific Publishers]
日期:2024-04-01
卷期号:16 (4): 468-474
标识
DOI:10.1166/sam.2024.4654
摘要
Bamboo activated carbon (BAC) has excellent specific capacitance among electrode materials, but the important challenges of it are the insufficient energy density and power density currently. Herein, a facile method for the preparation of strong performance MnO/Mn 3 O 4 /C composites by putting BAC into KMnO 4 solution and annealing in tube furnace. Interestingly, by controlling the reaction time and substrate concentration of BAC and KMnO 4 , it is possible to control not only the amount of MnO x doping, but also to change the ratio between MnO x , and thereby the electrochemical properties of MnO x /C was improved. Since BAC had a bilayer capacitance and manganese oxides could bring pseudo-capacitance to the materials, when the experimental conditions were reaction time and concentration of 20 min and 20 g/L respectively, the Mn content of the composite was 19.91% and it also had a excellent performance with 422.8 F/g of specific capacitance. In addition, the power and energy density were 30.76 Wh/kg and 3460 W/kg, respectively. It provided a basis for effectively improving the electrochemical performance of carbon-based electrode materials.
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