Late Paleozoic potassic igneous rocks of the Adyrtor intrusions in the eastern Kyrgyz Tien Shan: geochemistry, isotope U-Pb zircon geochronology, and related W-Mo(-Cu-Au) mineralization

The Adyrtor multiphase pluton is situated in the easternmost part of the 'Main Structural Line of Tien Shan', or the 'Nikolaev Line', and intrudes the Paleoproterozoic metamorphic sequence representing the oldest (1.8–2.5 Ga) continental basement fragment in the Tien Shan orogenic belt. The intrusions comprise mafic to intermediate (monzodiorite, monzonite, quartz syenite) and silicic (quartz monzonite, monzogranite, and leucogranite-alaskite) rocks. Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions, with a strong A-type granite affinity, emplaced in post-collisional setting. Based on the isotopic U-Pb data, quartz syenite from the Adyrtor intrusions crystallized at 330.7 ± 4.3 Ma, and quartz monzonite – at 329.5 ± 5.8 Ma. Although the ages identified correspond to those of the subduction-related magmatism in the western part of the Middle Tien Shan, geochemical characteristics of the rocks support rather post-collisional setting of the plutons, principally due to a 'scissor-like' closure of the Turkestan paleoocean, starting from the east. Magmatic evolution included a generation of shoshonitic magma by low-degree partial melting of the metasomatically-enriched upper mantle, followed by amphibole fractionation in a deep (lower crustal ?) magma chamber. Then, under the influence of mantle-supplied fluids and heat, granitic magmas in the crustal protolith could have been generated, with further mixing/mingling of the mantle-derived mafic (shoshonitic) magma and mantle-induced crustal granitic magma, followed by the magma fractionation and emplacement at shallower crustal levels. Assimilation of an old continental crust is also envisioned, consistent with the presence of the xenocrystic zircons dated at ca. 1.6 Ga to 2.5 Ga and the A-type granitoid affinity of the igneous rocks. The associated skarn-porphyry W-Mo(-Cu-Au) mineralization is consistent with post-collisional setting of the productive intrusions. This mineralization complements the group of similar deposits and occurrences associated with high-K calc-alkaline to shoshonitic series intrusions in the Middle Tien Shan and globally. The high endowment in W and Mo can be explained by the fertilization of subduction-modified subcontinental lithospheric mantle in these metals, with its further involvement in the magma generation in post-collisional setting. Also, a stronger W-Mo mineralization can reflect a greater role of a crustal protolith in the magma generation, as revealed by the distinct A-type affinity of the igneous rocks.