Sustainable organocatalytic cyanosilylation of ketones by PPM-level loading of triphenylcarbenium tetrakis(pentafluorophenyl)borate
化学
硼
催化作用
溶剂
有机化学
作者
Muhammad Israr,Han Yong Bae
出处
期刊:Green Chemistry [The Royal Society of Chemistry] 日期:2023-01-01卷期号:25 (6): 2387-2393被引量:6
标识
DOI:10.1039/d3gc00189j
摘要
We report herein solvent-free cyanosilylation of ketones catalyzed by 50 ppm of tritylium tetrakis(pentafluorophenyl)borate ([Ph3C]+[B(C6F5)4]−) as an extremely active organocatalyst.