四方晶系
镍
材料科学
合金
离解(化学)
催化作用
电解
氢
铟
金属
吸附
电极
化学工程
结晶学
化学
物理化学
晶体结构
冶金
电解质
工程类
有机化学
生物化学
作者
Surajit Mondal,Supriti Dutta,Santanu Mal,Swapan K. Pati,Sayan Bhattacharyya
标识
DOI:10.1002/anie.202301269
摘要
Abstract The immiscibility of crystallographic facets in multi‐metallic catalysts plays a key role in driving the green H 2 production by water electrolysis. The lattice mismatch between tetragonal In and face‐centered cubic ( fcc ) Ni is 14.9 % but the mismatch with hexagonal close‐packed ( hcp ) Ni is 49.8 %. Hence, in a series of Ni−In heterogeneous alloys, In is selectively incorporated in the fcc Ni. The 18–20 nm Ni particles have 36 wt % fcc phase, which increases to 86 % after In incorporation. The charge transfer from In to Ni, stabilizes the Ni 0 state and In develops a fractional positive charge that favors *OH adsorption. With only 5 at% In, 153 mL h −1 H 2 is evolved at −385 mV with mass activity of 57.5 A g −1 at—400 mV, 200 h stability at −0.18 V versus reversible hydrogen electrode (RHE), and Pt‐like activity at high current densities, due to the spontaneous water dissociation, lower activation energy barrier, optimal adsorption energy of OH − ions and the prevention of catalyst poisoning.
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