材料科学
形状记忆合金
复合材料
韧性
智能材料
聚丙烯酰胺
自愈水凝胶
硅酮
深共晶溶剂
溶剂
化学工程
硅油
纳米技术
共晶体系
高分子化学
有机化学
化学
合金
工程类
作者
Feng Yin,Qian Liu,Jun Hu,Yong Ju
标识
DOI:10.1021/acsami.3c17517
摘要
Shape memory gels, one of the primary modern smart materials, hold great promise in a myriad of applications spanning from soft robotics to medical devices. Nevertheless, most shape memory gels rely on water, organic solvents, and ionic liquids as dispersion mediums, posing the risks of freezing, dehydration, and toxicity to humans or environment. Herein, we have developed a thermoresponsive shape memory eutectogel by introducing an oleanolic acid-modified polyacrylamide network into a deep eutectic solvent (DES). The resulting eutectogel shows a fracture strength of 4.46 MPa along with elongation of 345%, Young's modulus of 14.83 MPa, and toughness of 9.51 MJ m–3. Thanks to the low freezing point and low volatility inherited from DES, this eutectogel possesses good antifreezing and long-term storage stability, which facilitate the shape memory behavior both in silicone oil and in air. The shape fixity and shape recovery ratios of this eutectogel maintain almost 90% during 10 cycles in silicone oil and more than 70% during four cycles in air that cannot be realized in hydrogels. By virtue of shape memory effect and conductivity, the eutectogel can be further used as a thermoswitch. This work presents a simple approach to fabricating shape memory eutectogels and imparts exciting prospects to smart eutectogels.
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