Recent Achievements in Organic Reactions in MeCN

Chapter 2 Recent Achievements in Organic Reactions in MeCN Tongtong Xing, Tongtong Xing Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorGuizhi Zhai, Guizhi Zhai Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorLinna Wu, Linna Wu Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorXiaofen Wang, Xiaofen Wang Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorZechao Wang, Zechao Wang Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this author Tongtong Xing, Tongtong Xing Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorGuizhi Zhai, Guizhi Zhai Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorLinna Wu, Linna Wu Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorXiaofen Wang, Xiaofen Wang Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this authorZechao Wang, Zechao Wang Zhengzhou University, Henan Institute of Advanced Technology, Division of Molecular Catalysis & Synthesis, No.100 Science Avenue, Zhengzhou, 450001 P. R. ChinaSearch for more papers by this author Book Editor(s):Xiao-Feng Wu, Xiao-Feng Wu Dalian Nat. Laboratory for Clean Energy, Dalian, 116023 Liaoning, ChinaSearch for more papers by this authorFeng Wang, Feng Wang Dalian Institute of Chemical Physics, Chinese Academy of Science, 457, Zhongshan Road, Dalian, 116023 ChinaSearch for more papers by this authorZhiping Yin, Zhiping Yin Jiangsu University, No. 301, Xuefu Road, Zhenjiang, 212013 ChinaSearch for more papers by this authorLiang-nian He, Liang-nian He Nankai University, No.94, Weijin Road, Tianjin, 300071 ChinaSearch for more papers by this author First published: 08 March 2024 https://doi.org/10.1002/9783527841943.ch2 AboutPDFPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShareShare a linkShare onEmailFacebookTwitterLinkedInRedditWechat Summary Acetonitrile, a colorless liquid, is highly volatile and has a special odor similar to ether. It has excellent solvent properties and can dissolve various organic, inorganic, and gaseous substances. It can undergo many chemical reactions and is used to prepare many typical nitrogen-containing compounds, making it an important organic intermediate. Acetonitrile can be used as a solvent for the synthesis of vitamin A, cortisone, carboamine drugs, and their intermediates, as well as an active medium solvent for the preparation of vitamin B1 and amino acids. Based on the diversity of acetonitrile in participating in chemical reactions, this chapter will introduce recent achievements in organic reactions in acetonitrile from the following three aspects: acetonitrile in transition metal-catalyzed reactions without radicals involved; acetonitrile in transition-metal-free catalyzed reactions without radicals involved; acetonitrile in C–X bond formation with radicals involved. References Robles , H. ( 2014 ). Encyclopedia of Toxicology , 3 e, 40 – 42 . Elsevier Inc. 10.1016/B978-0-12-386454-3.00624-2 Google Scholar Amoore , J.E. and Hautala , E. ( 1983 ). J. Appl. 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