The Effect of Yttria Content on Microstructure, Strength, and Fracture Behavior of Yttria-Stabilized Zirconia

Yttria-stabilized zirconia (YSZ) is well-known as a material with perfect mechanical, thermal, and electrical properties. It is used for manufacturing various high-temperature components for aerospace and energy generation, as well as wear- and corrosion-resistant devices in medicine. This work investigated the effect of a Y2O3 addition to ZrO2 on the microstructure and mechanical properties of YSZ ceramics produced by one sintering schedule. ZrO2 ceramics doped with 3, 4, 5, 6, 7, and 8 mol% Y2O3 (designated 3YSZ through to 8YSZ) were prepared by using conventional sintering at 1550 °C for 2 h in argon. The effect of yttria content was analyzed with respect to grain size, morphology of the microstructural features, phase composition, parameters of fracture surface, and flexural strength. The 7YSZ ceramics sintered at 1550 °C for 2 h showed the highest level of flexural strength due to the formation of the fine-grained microstructure containing mainly the monoclinic and tetragonal zirconia phases. The fracture micromechanism in the studied YSZ ceramics is discussed.