A theoretical study on the donor ability adjustment of tris(2,4,6-trichlorophenyl)methyl-triarylamine (TTM-TPA) radicals aiming to develop better organic luminescent materials

Spin-unrestricted DFT and spin-unrestricted TDDFT calculations were performed to systematically investigate the correlation between the electron donating ability of donors and photophysical properties in D–A luminescent radicals.