Competitive Li+ Coordination in Ionogel Electrolytes for Enhanced Li‐Ion Transport Kinetics

Developing ionogel electrolytes based on ionic liquid instead of volatile liquid in gel polymer electrolytes is regarded to be effective to diminish safety concerns in terms of overheating and fire. Herein, a zwitterion-based copolymer matrix based on the copolymerization of trimethylolpropane ethoxylate triacrylate (ETPTA) and 2-methacryloyloxyethylphosphorylcholine (MPC, one typical zwitterion) is developed. It is shown that introducing zwitterions into ionogel electrolytes can effectively optimize local lithium-ion (Li