Oxygen evolution activity of nickel-based phosphates and effects of their electronic orbitals

Metal phosphate-type compounds have been utilized in diverse applications, and their distinctive chemical properties have recently opened avenues for their use as catalysts. Metal phosphates have previously demonstrated significant electrocatalytic activity for the anodic oxygen evolution reaction (OER) in electrochemical water splitting. However, the critical factors influencing OER electrocatalysis on Ni-based phosphates have been insufficiently explored. We herein demonstrate nickel (Ni)-based phosphates-monoclinic Ni