铋
电子顺磁共振
未成对电子
化学
结晶学
分子间力
顺磁性
氧化态
金属
核磁共振
分子
有机化学
凝聚态物理
物理
作者
Ryan J. Schwamm,Jeffrey R. Harmer,Matthias Lein,Christopher M. Fitchett,Simon Granville,Martyn P. Coles
标识
DOI:10.1002/anie.201504632
摘要
Abstract More than 80 years after Paneth’s report of dimethyl bismuth, the first monomeric Bi II radical that is stable in the solid state has been isolated and characterized. Reduction of the diamidobismuth(III) chloride Bi(NON Ar )Cl (NON Ar =[O(SiMe 2 NAr) 2 ] 2− ; Ar=2,6‐ i Pr 2 C 6 H 3 ) with magnesium affords the Bi II radical . Bi(NON Ar ). X‐ray crystallographic measurements are consistent with a two‐coordinate bismuth in the +2 oxidation state with no short intermolecular contacts, and solid‐state SQUID magnetic measurements indicate a paramagnetic compound with a single unpaired electron. EPR and density functional calculations show a metal‐centered radical with >90 % spin density in a p‐type orbital on bismuth.
科研通智能强力驱动
Strongly Powered by AbleSci AI