膜
离子
氢氧化物
离子交换
离子键合
冠醚
材料科学
离子运输机
溶剂化
离子液体
无机化学
化学
有机化学
催化作用
生物化学
作者
Xiaolin Ge,Yubin He,Michael D. Guiver,Liang Wu,Jin Ran,Zhengjin Yang,Tongwen Xu
标识
DOI:10.1002/adma.201506199
摘要
A new class of alkaline anion-exchange membranes containing mobile ion shuttles is developed. It is achieved by threading ionic linear guests into poly(crown ether) hosts via host–guest molecular interaction. The thermal- and pH-triggered shuttling of ionic linear guests remarkably increases the solvation-shell fluctuations in inactive hydrated hydroxide ion complexes (OH−(H2O)4) and accelerates the OH− transport. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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