ZIF‐67‐Derived 3D Hollow Mesoporous Crystalline Co3O4 Wrapped by 2D g‐C3N4 Nanosheets for Photocatalytic Removal of Nitric Oxide

ZIF-67-derived 3D hollow mesoporous crystalline Co₃ O₄ wrapped by 2D graphitic carbon nitride (g-C₃ N₄ ) nanosheets are prepared by low temperature annealing, and are used for the photocatalytic oxidation of nitric oxide (NO) at a concentration of 600 ppb. The p-n heterojunction between Co₃ O₄ and g-C₃ N₄ forms a spatial conductive network frame and results in a broad visible light response range. The hollow mesoporous structure of Co₃ O₄ contributes to the circulation and adsorption of NO, and the large specific surface area exposes abundant active sites for the reaction of active species. A maximum NO degradation efficiency of 57% is achieved by adjusting the mass of the Co₃ O₄ precursor. Cycling tests and X-ray diffraction indicate the high stability and recyclability of the composite, making it promising in environmental purification applications.