化学
二甲基过氧化酮
单萜
水解
立体化学
有机化学
作者
John Boukouvalas,Nicolas Lachance
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:1998-01-01
卷期号:1998 (01): 31-32
被引量:37
摘要
2-Trialkylsilyloxyfurans react rapidly with dimethyldioxirane at -78 °C to provide trialkylsilyl (Z)-4-oxo-2-alkenoates whose hydrolysis delivers γ-hydroxybutenolides with high efficiency; a short synthesis of a naturally occurring monoterpene γ-hydroxybutenolide (4) is reported.
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