光催化
吸附
化学
产量(工程)
氮氧化物
化学工程
核化学
材料科学
催化作用
有机化学
复合材料
工程类
燃烧
作者
Kai Qi,Jun Jie Jing,Guohui Dong,Pengna Li,Yu Huang
标识
DOI:10.1016/j.envres.2022.113405
摘要
Photocatalysis technology is used to remove the low concentration NO in recent years. However, the effect of this process is not very satisfactory. In this study, it was found that the prepositive NaOH solution could significantly improve the photocatalytic NO removal activity of g-C3N4. The apparent quantum yield of g-C3N4 in the NO removal process was increased 3.5 times by the prepositive NaOH solution. The reason is that there was a synergistic effect formed between the prepositive NaOH solution and the photocatalytic NO removal process. The prepositive NaOH solution not only could increase the humidity and pH value in the photocatalytic unit, but also could improve the adsorption ability of g-C3N4 for the H2O, NO, and O2. Moreover, the prepositive NaOH solution reduced the difficulty of the photogenerated carriers’ transport and the ·OH generation. This study provided a new idea for the removal of low-concentration NOx.
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