空位缺陷
选择性
光电效应
光催化
电子转移
吸附
材料科学
电子
光化学
化学
光电子学
纳米技术
化学物理
化学工程
结晶学
催化作用
物理化学
物理
有机化学
工程类
量子力学
作者
Xiaojun Luo,Ling Qiao,Shutong Zhang,Qiuju Li,Yuhan Liao,Sicheng Rao,Haopeng Liu,Yan Zhao
标识
DOI:10.1016/j.apsusc.2022.154184
摘要
Photocatalytc CO2 reduction, which is used to produce high-efficiency and selective olefiant (C2H4), involves significant challenges. In this study, an S-defect dual-site NiCo2S4 nanoflower assembled by using hollow tubes is synthesized. Under simulated sunlight in a gas–solid reaction system, the prepared material exhibits excellent selectivity and efficiency of photocatalytic C2H4 production. The C2H4 yields reach 80.5 μmol g−1 within 6 h and the corresponding selectivity achieves 57.1%, which are 2.5 and 2.0 times higher than those of NiCo2S4 without defects, respectively. By Carefully analyzing the structure and photoelectric property, we discover that the construction of S-defects into NiCo2S4 lattice serve as an electron trap, restricting carrier recombination and accelerating the transfer of more active electrons to CO2 molecular. The S-defects further enhance the CO2 adsorption capacity, contributing to CO2 molecular activation. This study presents a simple route for synthesizing high-performance photocatalysts for high-value C2H4 production.
科研通智能强力驱动
Strongly Powered by AbleSci AI