钌
化学
卟啉
三吡啶
芳基
光化学
利乐
猝灭(荧光)
激发态
电化学
荧光
自由基
电子转移
药物化学
金属
催化作用
物理化学
有机化学
电极
烷基
物理
盐(化学)
量子力学
核物理学
作者
Isabelle M. Dixon,Jean‐Paul Collin
摘要
Four diads consisting of a free-base or zinc aryl-porphyrin associated with two ruthenium(II) bis(terdentate) complexes (non-cyclometallated Ru ( N 6) or cylometallated Ru ( N 5 C )) have been synthesized. The strong electron-withdrawing properties of the Ru ( N 6) as compared to the Ru ( N 5 C ) complex have been illustrated by their electrochemical and spectroscopic properties. Emission spectra of the diads and the reference compounds have shown that very efficient fluorescence quenching occurs, probably by energy transfer processes from the porphyrin to the 3 MLCT excited state of the ruthenium unit.
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