容量损失
锂(药物)
背景(考古学)
电极
离子
材料科学
极限(数学)
制作
化学
电化学
数学
医学
物理化学
古生物学
有机化学
病理
数学分析
替代医学
内分泌学
生物
作者
Jake Christensen,John Newman
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2005-01-01
卷期号:152 (4): A818-A818
被引量:166
摘要
In lithium-ion cells, there are several different classes of capacity loss, both reversible and irreversible, that limit the cell's exploitable specific capacity and can lead to eventual cell failure. We attempt to clarify what is meant by capacity loss and cyclable lithium loss by defining these terms in the context of electrode state-of-charge restrictions. We define irreversible capacity loss as that associated with active material loss and define two types of reversible capacity loss associated with balanced and unbalanced side reactions. We also examine several methods of compensating for cyclable lithium loss associated with passive-film formation and calculate the effect each has on a cell's specific energy. Preforming the negative electrode, adding cyclable lithium to the positive electrode, and introducing lithium powder into the negative electrode appear to be the most attractive methods in terms of specific energy, but practical constraints such as fabrication cost must be evaluated to determine which is superior.
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