三聚氰酸
二甲胺
化学
分子
三聚氯氰
氢键
二甲基甲酰胺
结晶学
高分子化学
晶体结构
立体化学
有机化学
溶剂
三聚氰胺
作者
V.R. Pedireddi,D. Belhekar
出处
期刊:Tetrahedron
[Elsevier]
日期:2002-04-01
卷期号:58 (15): 2937-2941
被引量:45
标识
DOI:10.1016/s0040-4020(02)00202-8
摘要
Synthesis and molecular packing analysis of the crystal structures of three complexes of cyanuric acid with dimethylsulfoxide (DMSO), dimethylamine (DMA) and dimethylformamide (DMF) respectively, in a 2:2, 2:1 and 1:1 ratio has been reported. In all three molecular complexes, cyanuric acid molecules form molecular tapes through the formation of strong cyclic N–H⋯O hydrogen bonds between the adjacent molecules. These tapes are further arranged in two-dimensions yielding layered structures such that the guest molecules (DMSO, DMA and DMF) are being incorporated between the tapes.
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