化学
过渡金属
金属
碳纤维
有机合成
纳米技术
组合化学
有机化学
催化作用
复合数
复合材料
材料科学
作者
Abdur Rahim,Jia Feng,Zhenhua Gu
标识
DOI:10.1002/cjoc.201900180
摘要
Generation of carbon‐metal species is extremely important in transition metal‐catalyzed organic synthesis. Among the various methods, 1,4‐metal migration is a very useful way to create new carbon‐metal species, which are not readily accessible via classic methods. This review summarized recent advances in transition metal‐catalyzed reactions, which involved one or more steps of 1,4‐metal migration. It focused mostly on the achievements in Pd and Rh‐catalyzed reactions, along with some of the remarkable results in Pt, Ir, Co, Fe‐involved transformations.
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