化学
溴
卟啉
锂(药物)
有机化学
光化学
药物化学
医学
内分泌学
作者
Emel Önal,Vefa Ahsen,Jacques Pécaut,Dominique Luneau,Catherine Hirel
标识
DOI:10.1016/j.tetlet.2015.07.021
摘要
A three step, one-pot reaction has been developed for the introduction of the formyl functional group to the meso position of porphyrins. Symmetric meso-tetrakis(4-formylphenyl)porphyrin ((CHO)4TPPH2), an important cornerstone in porphyrin chemistry, was obtained selectively in good yields via bromine–lithium exchange and subsequent Bouveault reaction. The meso-tetrakis(4-formylphenyl)porphyrin was fully characterized by HR-ESI, UV–vis, NMR, and single crystal X-ray diffraction.
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