Palladium-catalyzed domino Heck-disilylation and -borylation of alkene-tethered 2-(2-halophenyl)-1H-indoles: access to diverse disilylated and borylated indolo[2,1-a]isoquinolines

A chemoselective domino Heck-disilylation and -borylation reaction for generating various disilylated and borylated tetracyclic indolo[2,1-a]isoquinolines has been developed.