Soft-Carbon-Coated, Free-Standing, Low-Defect, Hard-Carbon Anode To Achieve a 94% Initial Coulombic Efficiency for Sodium-Ion Batteries

材料科学 法拉第效率 阳极 碳纤维 离子 电极 纳米技术 复合材料 复合数 化学 有机化学 冶金 物理化学
作者
Xiang‐Xi He,Jiahua Zhao,Wei‐Hong Lai,Rongrong Li,Zhuo Yang,C. W. Xu,Yingying Dai,Yun Gao,Xiao-Hao Liu,Li Li,Gang Xu,Yun Qiao,Shulei Chou,Minghong Wu
出处
期刊:ACS Applied Materials & Interfaces [American Chemical Society]
卷期号:13 (37): 44358-44368 被引量:84
标识
DOI:10.1021/acsami.1c12171
摘要

Developing hard carbon with a high initial Coulombic efficiency (ICE) and very good cycling stability is of great importance for practical sodium-ion batteries (SIBs). Defects and oxygen-containing groups grown along either the carbon edges or the layers, however, are inevitable in hard carbon and can cause a tremendous density of irreversible Na+ sites, decreasing the efficiency and therefore causing failure of the battery. Thus, eliminating these unexpected defect structures is significant for enhancing the battery performance. Herein, we develop a strategy of applying a soft-carbon coating onto free-standing hard-carbon electrodes, which greatly hinders the formation of defects and oxygen-containing groups on hard carbon. The electrochemical results show that the soft-carbon-coated, free-standing hard-carbon electrodes can achieve an ultrahigh ICE of 94.1% and long cycling performance (99% capacity retention after 100 cycles at a current density of 20 mA g–1), demonstrating their great potential in practical sodium storage systems. The sodium storage mechanism was also investigated by operando Raman spectroscopy. Our sodium storage mechanism extends the "adsorption–intercalation–pore filling–deposition" model. We propose that the pore filling in the plateau area might be divided into two parts: (1) sodium could fill in the pores near the inner wall of the carbon layer; (2) when the sodium in the inner wall pores is close to saturation, the sodium could be further deposited onto the existing sodium.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
大智若于完成签到 ,获得积分10
刚刚
HH应助香烟小厨采纳,获得10
刚刚
lhuh完成签到,获得积分20
1秒前
cjj完成签到,获得积分10
3秒前
winterm发布了新的文献求助10
4秒前
taozhiqi完成签到 ,获得积分10
6秒前
冷傲老九完成签到,获得积分10
7秒前
xiangzq完成签到,获得积分10
7秒前
隐形曼青应助隐形之玉采纳,获得10
7秒前
9秒前
0x1orz完成签到,获得积分10
10秒前
研友_Z1x9ln完成签到,获得积分10
13秒前
17秒前
yehaidadao完成签到,获得积分10
18秒前
111发布了新的文献求助10
20秒前
hj456完成签到,获得积分10
21秒前
21秒前
SIRT1发布了新的文献求助10
21秒前
26秒前
泡泡驳回了今后应助
27秒前
NexusExplorer应助SIRT1采纳,获得10
28秒前
0128lun完成签到,获得积分10
28秒前
lhuh发布了新的文献求助10
29秒前
kyt完成签到 ,获得积分10
29秒前
隐形之玉发布了新的文献求助10
30秒前
yaoccccchen完成签到,获得积分10
31秒前
zhaoyang完成签到 ,获得积分10
31秒前
111完成签到,获得积分10
31秒前
慕青应助不许内耗采纳,获得10
36秒前
啦啦啦发布了新的文献求助10
36秒前
感谢有你完成签到 ,获得积分10
37秒前
稳重的山柏完成签到 ,获得积分20
38秒前
38秒前
yif完成签到 ,获得积分10
39秒前
sherry221应助strings采纳,获得20
39秒前
奇奇吃面发布了新的文献求助10
41秒前
小卷粉完成签到 ,获得积分10
45秒前
刘小天完成签到,获得积分10
45秒前
45秒前
48秒前
高分求助中
Sustainability in Tides Chemistry 2800
Kinetics of the Esterification Between 2-[(4-hydroxybutoxy)carbonyl] Benzoic Acid with 1,4-Butanediol: Tetrabutyl Orthotitanate as Catalyst 1000
The Young builders of New china : the visit of the delegation of the WFDY to the Chinese People's Republic 1000
Rechtsphilosophie 1000
Bayesian Models of Cognition:Reverse Engineering the Mind 888
Handbook of Qualitative Cross-Cultural Research Methods 600
Very-high-order BVD Schemes Using β-variable THINC Method 568
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3137627
求助须知:如何正确求助?哪些是违规求助? 2788531
关于积分的说明 7787471
捐赠科研通 2444861
什么是DOI,文献DOI怎么找? 1300119
科研通“疑难数据库(出版商)”最低求助积分说明 625814
版权声明 601023