A comparative study of [Ag11(iPrS)9(dppb)3]2+ and [Ag15S(sBuS)12(dppb)3]+: templating effect on structure and photoluminescence

A comparative study of [Ag₁₁(ⁱPrS)₉(dppb)₃]²⁺ and [Ag₁₅S(^sBuS)₁₂(dppb)₃]⁺ was conducted to elucidate the templating effects of an S²⁻ anion on the geometrical structure and photoluminescence of silver(i) thiolate clusters.