拉曼光谱
石墨烯
材料科学
天顶
光谱学
光学
纳米技术
物理
天文
作者
Yukui Zhang,Tao Chen,Miao‐Ling Lin,Xiao‐Li Li,Xue‐Lu Liu,Ping‐Heng Tan
出处
期刊:Carbon
[Elsevier]
日期:2022-05-01
卷期号:191: 471-476
被引量:2
标识
DOI:10.1016/j.carbon.2022.02.012
摘要
Angle resolved polarized Raman (ARPR) spectroscopy has been widely used to study basic properties of two-dimensional materials (2DMs), such as underlying symmetry, mode assignment, crystallographic orientation and optical anisotropy. The substrate effect has never been uncovered in ARPR spectroscopy. In this work, we investigated zenith-angle resolved polarized Raman (ZRPR) spectra of the G mode of graphene (1LG) deposited on different substrates as well as graphite under in-plane and out-of-plane configurations. In contrast to the independent behavior in normal incidence geometry, the G mode intensity exhibits obvious zenith-angle dependence. In particular, this polarization behavior is sensitive to the underlying substrates underneath 1LG. The ZRPR intensity of the G mode can be well understood by a model considering both Raman selection rule and zenith-angle resolved interference effect. This work enriches the understanding of polarized Raman spectroscopy of 2DMs and the approach can be applicable to other 2DMs, especially in-plane anisotropic 2DMs.
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