Hierarchically Designed Three-Dimensional Composite Structure on a Cellulose-Based Solar Steam Generator

The emerging water purification technology represented by solar water evaporation has developed rapidly in recent years and is widely used in seawater desalination. However, the high reflectivity of sunlight and low efficiency of photothermal conversion greatly hinder its application prospects. In this paper, the hierarchical structure of the film was designed and optimized by the addition of carbon materials in the process of bacterial cellulose culture. A cellulose-based composite film material with a microporous structure was obtained, which can improve the photothermal evaporation rate and photothermal conversion efficiency from the structural principle to improve the stability of floating on the water. Bacterial cellulose (BC) as a three-dimensional carrier was combined with one-dimensional and two-dimensional (1D/2D) compounds of carbon nanotubes (CNT) and reduced graphene oxide (RGO) to form composite films for solar evaporation. By the addition of CNT-RGO (21.8 wt %), the composite showed prominent photothermal evaporation rate and photothermal conversion efficiency properties. Through in situ culture of BC, not only a tight structure can be obtained but also the surface of BC contains a large number of hydroxyl groups, which have many active sites to load photothermal materials. BC nanofibers, CNT, and RGO cooperate to form a porous network structure, which provides continuous double channels for the rapid transmission of water molecules and light paths, so as to form an excellent photothermal layer. The photothermal conversion efficiency is 90.2%, and the photothermal evaporation rate is 1.85 kg m-2 h-1 to achieve efficient solar interface evaporation. This is a high level of photothermal properties in a cellulose-based solar steam generator. The superior photothermal performance of this hybrid film possesses scalability and desalination ability.