电催化剂
碳化
电解水
电解
分解水
材料科学
催化作用
化学工程
多孔性
制氢
聚合物
碳纤维
纳米技术
化学
有机化学
电化学
电极
复合材料
电解质
工程类
物理化学
复合数
光催化
扫描电子显微镜
作者
Dong Won Kang,Minki Jun,Jun Kim,Heesu Yang,Taehyun Kwon,Jinwhan Joo,Hyojin Kim,Min‐Jung Kang,Jin Young Kim,Kwangyeol Lee,Chang Seop Hong
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2022-03-08
卷期号:5 (3): 3269-3274
被引量:10
标识
DOI:10.1021/acsaem.1c03887
摘要
Water electrolysis shows great promise as a viable pathway for the scalable production of high-purity hydrogen, a clean and renewable energy source. Despite being extensively developed for water splitting, scalable electrocatalysts that can balance catalytic activity and cost-effectiveness continue to be in great demand. Herein, we report a low Pt content electrocatalyst based on a N-doped carbon matrix derived from a hypercrosslinked porous organic polymer (HCP). The HCP was prepared through double Friedel–Crafts reactions with improved porosity for the first time. After Pt metallization and carbonization, a scalable electrocatalyst was obtained without other capping and reducing agents. The prepared catalyst exhibited top-tier performances in catalytic activity and durability in hydrogen evolution reaction when compared to previously reported metal–organic framework- and covalent organic framework-based catalysts. In addition, a water splitting cell using a porous material was demonstrated for the first time. This work provides insight into the design of a scalable electrocatalyst for the generation of hydrogen from water electrolysis.
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