材料科学
微观结构
共晶体系
扫描电子显微镜
粒度
光学显微镜
透射电子显微镜
冶金
铸造厂
体积分数
化学工程
复合材料
纳米技术
工程类
作者
Jiyao Li,Xun Zhang,Johannes Winklhofer,Stefan Griesebner,Bernd Oberdorfer,Wanqi Jie,Peter Schumacher
出处
期刊:Solid State Phenomena
日期:2022-01-10
卷期号:327: 207-222
标识
DOI:10.4028/www.scientific.net/ssp.327.207
摘要
In order to reduce CO 2 emission and energy consumption, more recycled secondary materials have to be used in foundry industry, especially for Al-Si-Mg based alloys for semi-solid processing. In this paper, Al-Si-Mg based alloys with the addition of recycled secondary materials up to 30 % (10, 20, 30 %, respectively) have been produced by semi-solid processing. The solidification microstructure was investigated using optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Furthermore, computed tomography (CT) was also used to elucidate the size, size distribution, number density, volume fraction of porosities. It was found that with the addition of the recycled secondary materials up to 30 %, there is no significant effect on the solidification microstructure in terms of the grain size and the shape factor of primary α-Al and the second α-Al. More importantly, the morphology of eutectic Si can be well modified and that of the Fe-containing phase (π-AlSiMgFe) can be tailored. Furthermore, with increasing recycled secondary materials, at least another two important issues should also be highlighted. Firstly, more TiB 2 particles were observed, which can be due to the addition of Al-Ti-B grain refiners for the grain refinement of recycled secondary materials. Secondly, a significant interaction between Sr and P was also observed in the recycled secondary materials. The present investigation clearly demonstrates that Al-Si-Mg based alloys with the addition of recycled secondary materials at least up to 30% can be used for semi-solid processing, which may facilitate better sustainability.
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