Solvatochromism as a probe to observe the solvent exchange process in a 1-D porous coordination polymer with 1-D solvent accessible channels

A one-dimensional porous coordination polymer possessing pleochroic and solvatochromic properties produces an unexpected double V-shaped discolouration of the crystal upon solvent exchange with acetonitrile and nitromethane. Modelling shows that the origin of this effect is preferential sorption at two faces of the crystal.