荧光粉
机械容积
光致发光
热释光
余辉
分析化学(期刊)
发光
四方晶系
兴奋剂
发射光谱
离子
材料科学
光谱学
矿物学
化学
晶体结构
谱线
结晶学
光电子学
物理
伽马射线暴
色谱法
量子力学
天文
有机化学
作者
Ishwar Prasad Sahu,D. P. Bisen,K. V. R. Murthy,Raunak Kumar Tamrakar
出处
期刊:Luminescence
[Wiley]
日期:2017-05-29
卷期号:32 (7): 1263-1276
被引量:10
摘要
Abstract Ca 2 MgSi 2 O 7 :Ce 3+ , Ca 2 MgSi 2 O 7 :Eu 2+ and Ca 2 MgSi 2 O 7 :Eu 2+ ,Ce 3+ phosphors were prepared using the solid‐state reaction method. The crystal structures of the sintered phosphors were of melilite type, which has a tetragonal crystallography. The chemical compositions of the sintered phosphors was confirmed by energy dispersive X‐ray spectroscopy. The different thermoluminescence kinetic parameters [activation energy ( E ), frequency factor ( s ) and order of the kinetics ( b )] of these phosphors were evaluated and compared using the peak shape method. Under ultraviolet excitation, the emission spectra of both Ca 2 MgSi 2 O 7 :Eu 2+ and Ca 2 MgSi 2 O 7 :Eu 2+ ,Ce 3+ phosphors were composed of a broad emission band peaking at 530 nm. When the Ca 2 MgSi 2 O 7 :Eu 2+ phosphor is co‐doped with Ce 3+ ions, photoluminescence, afterglow and mechanoluminescence intensity was strongly enhanced. Ca 2 MgSi 2 O 7 :Eu 2+ showed some afterglow with a short persist time. On incorporation of Ce 3+ , efficient energy transfer from Ce 3+ to Eu 2+ was found and the emission intensity of Eu 2+ was enhanced. The mechanoluminescence intensities of Ca 2 MgSi 2 O 7 :Ce 3+ , Ca 2 MgSi 2 O 7 :Eu 2+ and Ca 2 MgSi 2 O 7 :Eu 2+ ,Ce 3+ phosphors increased proportionally increased with the increase in impact velocity, which suggests that these phosphors can be used as sensors to detect stress in an object.
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